Current Distributions and Electrode Shape Changes in Electrochemical Systems

Download or read book Current Distributions and Electrode Shape Changes in Electrochemical Systems written by Johan Deconinck and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 299 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reponds to the increasing demand of computer mo- delling of electrochemical processes in order to improve their speed and efficiency. The fundamental transport equa- tions in dilute solutions are given and it is established in detail under what circumstances a potential model with non- linear boundary conditions, involved by electrode reactions, can beused. Attention is directed towards the most impor- tant solution techniquesFEM, FDM and BEM and towards the solution of the non-linear system of equations (Successive Substitution, Newton-Raphson). Using the BEM, several two- dimensional and axisymmetrical examples of current density distributions are given and quantitative data, obtained in a copper electro-refining cell, are compared with calculated results. Applying Faraday's Law and the BEM, simulation of electro-deposition, electro-chemical levelling and machining are treated. Accuracy and stabilityare emphasized.